Aligning one's chakras isn't that difficult, really. Just practice your savasana (Corpse Pose). Although I can see how aligning with someone else's chakras might be a touch more difficult.

The real trouble, though, is getting one's chakras to open fully.

I'm not sure the whole chakra theory completely holds water, but there's a pretty undeniable mind-body connection that seems to give the whole thing credence.